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. Structural correspondence between the α-helix and the random-flight chain resolves how unfolded proteins can have native-like properties
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. This process may ensue in widespread deformations of the native fold with the creation of a large number of ANS binding pockets
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. A surprising result is the rank order of the kinetic disk stability ΔG* ~ln τ that is evident from the timescales of the heat denaturation, apoA-1 > apoA-2 > apoC-1 (Fig
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. Several general predictions result: 1), intermediate subspaces of configurations will always be visited; 2), specific but nonnative interactions may be important in stabilizing these low-dimensional diffusive searches on the folding pathway, as well as native interactions; 3), sequential barriers will commonly be found, even in "two-state" proteins; 4), very early times will show characteristic departures from single-exponential kinetics; and 5), contributions of nonnative interactions to Φ-values and "Chevron plots" are calculable, and may be significant
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