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. The values of K^sub SV^ for Trp residues in proteins and for free Trp in aqueous solution are not directly comparable
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. Our data therefore indicate that unfolded states exhibit a larger red shift of the fluorescence emission spectrum when theses states under the respective conditions are less susceptible for aggregation
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. Upon Ca^sup 2+^ binding, a conformational change enables it to interact with over 100 different target proteins, including transcription factors (for reviews, see Van Eldik and Watterson and others (6,7))
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. Again, S = 0 for a perfect sphere
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