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. Dielectric spectroscopy provides direct information of the dynamic behavior of molecular dipole orientation in solution
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. This is the case if at least one major component of the surrounding solvent is chemically equivalent to the main repeating unit of the polymer making chain-solvent contacts preferable to chain-chain contacts (4,37)
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. The fluorescence emission of the folded state is already rather blue shifted (λ^sub max^ = 327 nm), but also rather large λ^sub max^-values (341-344 nm) for the unfolded states contribute significantly to the large red shift
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. Furthermore, the conformational scrambling of both unfolded states might be different due to different mechanisms of denaturing the proteins
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. © 2005 by the Biophysical Society0006-3495/05/08/1214/13 $2
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. However, we obtained no useful information on the glass transition temperature T^sub g^
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. Our data on T^sub g^ of the IPP polymers (9 to 13°C) are consistent with reference 3, which reported that the T^sub g^ of IPP polymer ranges from about -30 to +20°C and depends on tacticity and thermal history
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